JPS6247410B2 - - Google Patents
Info
- Publication number
- JPS6247410B2 JPS6247410B2 JP58206101A JP20610183A JPS6247410B2 JP S6247410 B2 JPS6247410 B2 JP S6247410B2 JP 58206101 A JP58206101 A JP 58206101A JP 20610183 A JP20610183 A JP 20610183A JP S6247410 B2 JPS6247410 B2 JP S6247410B2
- Authority
- JP
- Japan
- Prior art keywords
- mercury
- ions
- thiosulfate
- composition
- liquid carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 46
- 239000000203 mixture Substances 0.000 claims description 29
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 17
- -1 thiosulfate ions Chemical class 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 13
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 10
- 229910001431 copper ion Inorganic materials 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical group C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- HCGFUIQPSOCUHI-UHFFFAOYSA-N 2-propan-2-yloxyethanol Chemical compound CC(C)OCCO HCGFUIQPSOCUHI-UHFFFAOYSA-N 0.000 claims 1
- 125000003158 alcohol group Chemical group 0.000 claims 1
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 claims 1
- FGRVOLIFQGXPCT-UHFFFAOYSA-L dipotassium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [K+].[K+].[O-]S([O-])(=O)=S FGRVOLIFQGXPCT-UHFFFAOYSA-L 0.000 claims 1
- 229910052753 mercury Inorganic materials 0.000 description 35
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 239000003610 charcoal Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 4
- 239000011630 iodine Substances 0.000 description 4
- 229910052740 iodine Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229960000355 copper sulfate Drugs 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- 239000002594 sorbent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 208000012902 Nervous system disease Diseases 0.000 description 1
- 208000025966 Neurological disease Diseases 0.000 description 1
- 206010062237 Renal impairment Diseases 0.000 description 1
- ZSILVJLXKHGNPL-UHFFFAOYSA-L S(=S)(=O)([O-])[O-].[Ag+2] Chemical compound S(=S)(=O)([O-])[O-].[Ag+2] ZSILVJLXKHGNPL-UHFFFAOYSA-L 0.000 description 1
- DNNYFEFWVHIYCJ-UHFFFAOYSA-K S(=S)(=O)([O-])[O-].[Cu+3].[I-] Chemical compound S(=S)(=O)([O-])[O-].[Cu+3].[I-] DNNYFEFWVHIYCJ-UHFFFAOYSA-K 0.000 description 1
- 238000009621 Solvay process Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000006931 brain damage Effects 0.000 description 1
- 231100000874 brain damage Toxicity 0.000 description 1
- 208000029028 brain injury Diseases 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 1
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000005977 kidney dysfunction Effects 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 150000002730 mercury Chemical class 0.000 description 1
- QKEOZZYXWAIQFO-UHFFFAOYSA-M mercury(1+);iodide Chemical compound [Hg]I QKEOZZYXWAIQFO-UHFFFAOYSA-M 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000012806 monitoring device Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000035935 pregnancy Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S210/00—Liquid purification or separation
- Y10S210/902—Materials removed
- Y10S210/911—Cumulative poison
- Y10S210/912—Heavy metal
- Y10S210/914—Mercury
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000414904A CA1203525A (en) | 1982-11-04 | 1982-11-04 | Mercury vapour suppressant |
| CA414904 | 1982-11-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59136122A JPS59136122A (ja) | 1984-08-04 |
| JPS6247410B2 true JPS6247410B2 (en]) | 1987-10-07 |
Family
ID=4123886
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58206101A Granted JPS59136122A (ja) | 1982-11-04 | 1983-11-04 | 水銀蒸気吸収組成物 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4534944A (en]) |
| JP (1) | JPS59136122A (en]) |
| CA (1) | CA1203525A (en]) |
| GB (1) | GB2134093B (en]) |
| SE (1) | SE455270B (en]) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61222525A (ja) * | 1985-03-28 | 1986-10-03 | Tokyo Met Gov Kankyo Seibi Koushiya | 水銀を含んだ排出ガスの清浄化方法 |
| CA1275284C (en) * | 1986-10-03 | 1990-10-16 | Richard H. Roydhouse | Composition to absorb mercury |
| US4876025A (en) * | 1986-10-03 | 1989-10-24 | Eps Environmental Protection Systems Limited | Composition to absorb mercury |
| US5093024A (en) * | 1988-09-08 | 1992-03-03 | Eps Environmental Protection Systems Limited | Composition able to absorb mercury vapor and to disinfect a surface |
| ES2051342T3 (es) * | 1988-10-28 | 1994-06-16 | Ftu Gmbh | Agentes y procedimiento para la purificacion de gases y gases de escape respecto de metales pesados, y un procedimiento para la preparacion de estos agentes. |
| US5209912A (en) * | 1990-05-02 | 1993-05-11 | Ftu Gmbh | Process for separating out noxious substances from gases and exhaust gases |
| US5173286A (en) * | 1991-07-19 | 1992-12-22 | Mobil Oil Corporation | Fixation of elemental mercury present in spent molecular sieve desiccant for disposal |
| ES2133377T3 (es) * | 1991-11-27 | 1999-09-16 | Calgon Carbon Corp | Carbon de respirador universal activado, impregnado, exento de cromo para la adsorcion de gases y/o vapores toxicos. |
| DE29608000U1 (de) * | 1996-05-03 | 1996-08-01 | Bittner Brigitte | Mittel zur Mund- und/oder Zahnpflege |
| WO2008008475A2 (en) * | 2006-07-11 | 2008-01-17 | Solucorp Industries, Ltd. | Process for the removal of mercury from gases |
| WO2012177210A1 (en) * | 2011-06-21 | 2012-12-27 | Pharmalundensis Ab | Activated carbon comprising an adsorbed iodide salt for use in the reduction of gastrointestinal uptake of mercury |
| WO2013081692A1 (en) * | 2011-11-29 | 2013-06-06 | Vaporlok Technology, Llc | Mercury capture for packager fluorescent lamps |
| US8974581B2 (en) * | 2011-11-29 | 2015-03-10 | Vaporlok Technology, Llc | Mercury capture for packaged fluorescent lamps |
| CN104507551B (zh) * | 2012-08-20 | 2018-08-07 | 艺康美国股份有限公司 | 汞吸附剂 |
| CN104645928B (zh) * | 2013-11-25 | 2018-03-06 | 北京三聚环保新材料股份有限公司 | 银系脱汞剂的制备方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3875287A (en) * | 1972-08-15 | 1975-04-01 | Toho Zinc Co Ltd | Removing mercury from concentrated sulfuric acid using iodides |
| DE2656803C2 (de) * | 1975-12-18 | 1986-12-18 | Institut Français du Pétrole, Rueil-Malmaison, Hauts-de-Seine | Verfahren zur Entfernung von in einem Gas oder in einer Flüssigkeit vorhandenem Quecksilber |
| US4210437A (en) * | 1978-12-14 | 1980-07-01 | Standard Oil Company (Indiana) | Liquid fertilizer for supply of sulfur, nitrogen and micronutrient metals |
| US4369061A (en) * | 1979-12-28 | 1983-01-18 | Kerley Jr Bernard J | Recovery of precious metals from difficult ores |
| US4354942A (en) * | 1980-11-26 | 1982-10-19 | Olin Corporation | Stabilization of mercury in mercury-containing materials |
-
1982
- 1982-11-04 CA CA000414904A patent/CA1203525A/en not_active Expired
-
1983
- 1983-10-31 US US06/546,886 patent/US4534944A/en not_active Expired - Lifetime
- 1983-10-31 GB GB08328984A patent/GB2134093B/en not_active Expired
- 1983-11-03 SE SE8306038A patent/SE455270B/sv not_active IP Right Cessation
- 1983-11-04 JP JP58206101A patent/JPS59136122A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| SE8306038D0 (sv) | 1983-11-03 |
| US4534944A (en) | 1985-08-13 |
| GB2134093B (en) | 1986-05-29 |
| SE455270B (sv) | 1988-07-04 |
| JPS59136122A (ja) | 1984-08-04 |
| CA1203525A (en) | 1986-04-22 |
| GB8328984D0 (en) | 1983-11-30 |
| SE8306038L (sv) | 1984-05-05 |
| GB2134093A (en) | 1984-08-08 |
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